Mysql - Performance with 0% efficiency

Question

My Mysql is very slow in queries, but these same queries made on the production server are fast. So moving here I found this screen as circled in red says that the efficiency is at 0% and production is at 99.8%. Is there any way to increase the efficiency on my machine? Will changing the file my.ini would solve?

Follow my file my.ini

[client] 
port            = 3306 
socket          = "C:/xampp/mysql/mysql.sock"
[mysqld]
port= 3306
socket = "C:/xampp/mysql/mysql.sock"
basedir = "C:/xampp/mysql" 
tmpdir = "C:/xampp/tmp" 
datadir = "C:/xampp/mysql/data"
pid_file = "mysql.pid"
key_buffer = 16M
max_allowed_packet = 32M
table_cache = 64
sort_buffer_size = 512K
net_buffer_length = 8K
read_buffer_size = 256K
read_rnd_buffer_size = 512K
myisam_sort_buffer_size = 8M
log_error = "mysql_error.log"
plugin_dir = "C:/xampp/mysql/data/lib/plugin/" 
skip-federated
server-id   = 1
innodb_data_home_dir = "C:/xampp/mysql/data"
innodb_data_file_path = ibdata1:10M:autoextend
innodb_log_group_home_dir = "C:/xampp/mysql/data"
innodb_buffer_pool_size = 16M
innodb_additional_mem_pool_size = 2M
innodb_log_file_size = 5M
innodb_log_buffer_size = 8M
innodb_flush_log_at_trx_commit = 1
innodb_lock_wait_timeout = 50
character_set_server=utf8
join_buffer_size = 256k
thread_cache_size = 9
flush_time = 0
default-storage-engine = InnoDB
open-files-limit = 4110
tmp_table_size = 30M

[mysqldump]
quick
max_allowed_packet = 16M

[mysql]
no-auto-rehash
[isamchk]
key_buffer = 20M
sort_buffer_size = 20M
read_buffer = 2M
write_buffer = 2M

[myisamchk]
key_buffer = 20M
sort_buffer_size = 20M
read_buffer = 2M
write_buffer = 2M

[mysqlhotcopy]
interactive-timeout

[client] 
port            = 3306 
socket          = "C:/xampp/mysql/mysql.sock"
[mysqld]
port= 3306
socket = "C:/xampp/mysql/mysql.sock"
basedir = "C:/xampp/mysql" 
tmpdir = "C:/xampp/tmp" 
datadir = "C:/xampp/mysql/data"
pid_file = "mysql.pid"
key_buffer = 16M
max_allowed_packet = 32M
table_cache = 64
sort_buffer_size = 512K
net_buffer_length = 8K
read_buffer_size = 256K
read_rnd_buffer_size = 512K
myisam_sort_buffer_size = 8M
log_error = "mysql_error.log"
plugin_dir = "C:/xampp/mysql/data/lib/plugin/" 
skip-federated
server-id   = 1
innodb_data_home_dir = "C:/xampp/mysql/data"
innodb_data_file_path = ibdata1:10M:autoextend
innodb_log_group_home_dir = "C:/xampp/mysql/data"
innodb_buffer_pool_size = 16M
innodb_additional_mem_pool_size = 2M
innodb_log_file_size = 5M
innodb_log_buffer_size = 8M
innodb_flush_log_at_trx_commit = 1
innodb_lock_wait_timeout = 50
character_set_server=utf8
join_buffer_size = 256k
thread_cache_size = 9
flush_time = 0
default-storage-engine = InnoDB
open-files-limit = 4110
tmp_table_size = 30M

[mysqldump]
quick
max_allowed_packet = 16M

[mysql]

[isamchk]
key_buffer = 20M
sort_buffer_size = 20M
read_buffer = 2M
write_buffer = 2M

[myisamchk]
key_buffer = 20M
sort_buffer_size = 20M
read_buffer = 2M
write_buffer = 2M

[mysqlhotcopy]
interactive-timeout

Edit

Below the production screen with 99.8% efficiency. I picked up at the time the queries (SELECTS) were at zero.