Binaria tree with 3 pointers has special treatment?

Question

I am setting up a hospital program and the order of the patients will be by a binary tree, taking into account a degree of urgency existing in the patient struct, as shown below. My question is: Do you have any special treatment for 3 pointers? Because when I run the program it seems that it is not saved in the tree structure when I try to show the tree in order it is always empty.

Structs of patient and tree:

typedef struct Paciente{
    char nome[50];
    char cpf[50];
    char sexo[20];
    char sintomas[500];
    int telefone;
    int idade;
    int codi;
    int urg;
    struct Paciente *prox;
}paciente;

typedef struct Arvore{
    struct Paciente *No;
    struct Arvore *Esq;
    struct Arvore *Dir;
}arvore;

Add and Show tree functions:

void adicionar(arvore **Arv, paciente *pac){
    arvore *temp = NULL;
    if (*Arv == NULL){
        temp = (arvore*)malloc(sizeof(arvore));
        temp->Esq = NULL;
        temp->Dir = NULL;
        temp->No = pac;
        *Arv = temp;
    }
    else {
        if (pac->urg < ((*Arv)->No->urg)){
            adicionar(&((*Arv)->Esq), pac);
        }
        else{
            adicionar(&((*Arv)->Dir), pac);
        }
    }
}

// Em Ordem (Do menor pro maior)
void Mostrar(arvore *Arv){
    if(Arv != NULL){
        Mostrar(Arv->Esq);
        printf("Nome: %s\nCPF: %s\nSexo: %s\nIdade: %d\nTelefone: %d\nSintomas: %s\nUrgencia: %d\nCódigo: %d\n", Arv->No->nome, Arv->No->cpf, Arv->No->sexo, Arv->No->idade, Arv->No->telefone, Arv->No->sintomas, Arv->No->urg, Arv->No->codi);
        Mostrar(Arv->Dir);
    }
}

On Main I create it like this:

arvore *Arv = NULL;