How to send this XML to webservice via PHP

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Good morning, I have the following problem:

I need to remove from the city website which companies issued note this month.

I did the processes of installing the certificate of the city, and I need the answer of this xml:

<?xml version="1.0" encoding="utf-8"?>
<soap:Envelope xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:xsd="http://www.w3.org/2001/XMLSchema" xmlns:soap="http://schemas.xmlsoap.org/soap/envelope/">
  <soap:Body>
    <BuscarUsuario xmlns="http://www.e-governeapps2.com.br/">
      <imu>string</imu>
      <cnpj>string</cnpj>
    </BuscarUsuario>
  </soap:Body>
</soap:Envelope>

I stopped here, I can’t send, let alone give the certificate, some hint where to search this?

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