Yes, can be used outside the element <head>, but it depends on the use. To import a CSS file, as mentioned, it is recommended to leave it at the top of the document, inside the element <head> for various considerations.
There are types of <link> that are considered body-ok that, when possessing one of these types, it is acceptable (or expected) that the element is in the HTML body. It is they: 
- dns-prefetch
- modulepreload
- pingback
- preconnect
- prefetch
- preload
- prerender
- stylesheet
In addition, the most common use of the element <link> in the <body> is when he uses the attributes itemprop to assist in the construction of the document’s Microdata. For example, the schema product brings the following example:
<div itemscope itemtype="http://schema.org/ItemList">
  <link itemprop="url" href="http://multivarki.ru?filters%5Bprice%5D%5BLTE%5D=39600" />
  <span itemprop="numberOfItems">315</span>
  <div itemprop="itemListElement" itemscope itemtype="http://schema.org/Product">
    <img alt="Photo of product" itemprop="image"
     src="http://img01.multivarki.ru.ru/c9/f1/a5fe6642-18d0-47ad-b038-6fca20f1c923.jpeg" />
    <a itemprop="url" href="http://multivarki.ru/brand_502/">
      <span itemprop="name">BRAND 502</span>
    </a>
    <div itemprop="offers" itemscope itemtype="http://schema.org/Offer">
      <span itemprop="price">4399 р.</span>
    </div>...
    <div itemprop="itemListElement" itemtype="http://schema.org/Product">
    ...
    </div>
  </div>
</div>
Or the schema event mixing the use of elements <link> and <meta>:
<div itemscope="" itemtype="http://schema.org/MusicEvent">
  <div itemprop="location" itemscope="" itemtype="http://schema.org/MusicVenue">
    <meta itemprop="name" content="Chicago Symphony Center"/>
    <link itemprop="sameAs" href="http://en.wikipedia.org/wiki/Symphony_Center"/>
    <meta itemprop="address" content="220 S. Michigan Ave, Chicago, Illinois, USA"/>
  </div>
  <div itemprop="offers" itemscope="" itemtype="http://schema.org/Offer">
    <link itemprop="url" href="/examples/ticket/12341234" />
    <meta itemprop="price" content="40"/>
    <meta itemprop="priceCurrency" content="USD" />
    <link itemprop="availability" href="http://schema.org/InStock"/>
  </div>
  <h2 itemprop="name">Shostakovich Leningrad</h2>
  <div>
    <div itemprop="startDate" content="2014-05-23T20:00">May<span>23</span></div>
    <div>8:00 PM</div>
    <div>
      <strong>Britten, Shostakovich</strong>
    </div>
  </div>
  <div>
    <p>Jaap van Zweden conducts two World War II-era pieces showcasing the glorious sound of the CSO.</p>
  </div>
  <div>
    <h3>Program</h3>
    <ul>
      <li itemprop="workPerformed" itemscope="" itemtype="http://schema.org/CreativeWork">
        <link itemprop="sameAs" href="http://en.wikipedia.org/wiki/Peter_Grimes" />
        <span itemprop="name"><strong>Britten</strong> Four Sea Interludes and Passacaglia from <em itemprop="name">Peter Grimes</em></span>
  </li>
      <li itemprop="workPerformed" itemscope="" itemtype="http://schema.org/CreativeWork">
      <link itemprop="sameAs" href="http://en.wikipedia.org/wiki/Symphony_No._7_(Shostakovich)" />
      <span itemprop="name"><strong>Shostakovich</strong> Symphony No. 7 <em>(Leningrad)</em></span>
  </li>
    </ul>
  </div>
  <div>
    <h3>Performers</h3>
    <div itemprop="performer" itemscope="" itemtype="http://schema.org/MusicGroup">
      <img src="/examples/cso_c_logo_s.jpg" alt="Chicago Symphony Orchestra" />
      <link itemprop="sameAs" href="http://cso.org/" />
      <link itemprop="sameAs" href="http://en.wikipedia.org/wiki/Chicago_Symphony_Orchestra" />
      <div>
        <a href="examples/Performer?id=4434"><span itemprop="name">Chicago Symphony Orchestra</span></a>
      </div>
    </div>
    <div itemprop="performer" itemscope="" itemtype="http://schema.org/Person">
      <link itemprop="sameAs" href="http://www.jaapvanzweden.com/" />
      <img itemprop="image" src="/examples/jvanzweden_s.jpg" alt="Jaap van Zweden"/>
      <div>
        <a href="/examples/Performer.aspx?id=11324"><span itemprop="name">Jaap van Zweden</span></a>
      </div>
      <div>conductor</div>
    </div>
  </div>
</div>