It has to be passed on subtract a corresponding duration which in your case is 03:00:00 (3 hours) with the command moment.duration, example:
var value = '/Date(1533227866063)/';
var datetime0 = moment(value)
console.log(datetime0.format("DD/MM/YYYY HH:mm:SS"));    
var time = moment.duration("03:00:00");
var datetime1 = moment(value);
datetime1.subtract(time);
console.log(datetime1.format("DD/MM/YYYY HH:mm:SS"));    
<script src="https://ajax.googleapis.com/ajax/libs/jquery/2.1.1/jquery.min.js"></script>
<script src="https://cdnjs.cloudflare.com/ajax/libs/moment.js/2.22.2/moment.min.js"></script>
 
 
It can also be passed by a direct setting on subtract one {h:3} which is the amount of hours, example:
var value = '/Date(1533227866063)/';
var datetime0 = moment(value)
console.log(datetime0.format("DD/MM/YYYY HH:mm:SS"));    
var datetime1 = moment(value);
datetime1.subtract({h:3});
console.log(datetime1.format("DD/MM/YYYY HH:mm:SS"));  
<script src="https://ajax.googleapis.com/ajax/libs/jquery/2.1.1/jquery.min.js"></script>
<script src="https://cdnjs.cloudflare.com/ajax/libs/moment.js/2.22.2/moment.min.js"></script>
 
 
this being very direct to what needs to subtract.
Another way is also using the two parameters example:
var value = '/Date(1533227866063)/';
var datetime0 = moment(value)
console.log(datetime0.format("DD/MM/YYYY HH:mm:SS"));    
var time = moment.duration("03:00:00");
var datetime1 = moment(value);
datetime1.subtract(3, 'hours');
console.log(datetime1.format("DD/MM/YYYY HH:mm:SS"));  
<script src="https://ajax.googleapis.com/ajax/libs/jquery/2.1.1/jquery.min.js"></script>
<script src="https://cdnjs.cloudflare.com/ajax/libs/moment.js/2.22.2/moment.min.js"></script>
 
 
To add only changes the method but, the form is the same example:
var value = '/Date(1533227866063)/';
var datetime0 = moment(value)
console.log(datetime0.format("DD/MM/YYYY HH:mm:SS"));    
var time = moment.duration("03:00:00");
var datetime1 = moment(value);
datetime1.add(3, 'hours');
console.log(datetime1.format("DD/MM/YYYY HH:mm:SS"));  
<script src="https://ajax.googleapis.com/ajax/libs/jquery/2.1.1/jquery.min.js"></script>
<script src="https://cdnjs.cloudflare.com/ajax/libs/moment.js/2.22.2/moment.min.js"></script>
 
 
These are the possible ways to add/subtract with momentjs.
Your documentation has all this explained
moment().add(Number, String);
moment().add(Duration);
moment().add(Object);
moment().subtract(Number, String);
moment().subtract(Duration);
moment().subtract(Object);
the explanation of the parameters being as follows:
|---------------|-------------|
| Key           | Shorthand   |
|---------------|-------------|
| years         | y           |
| quarters      | Q           |
| months        | M           |
| weeks         | w           |
| days          | d           |
| hours         | h           |
| minutes       | m           |   
| seconds       | s           |
| milliseconds  | ms          |
|---------------|-------------|
Examples:
moment().add(7, 'days').add(1, 'months'); 
moment().add({days:7,months:1});
Examples and documentation on:
							
							
						 
You have the result of value 02/08/2018 13:37 and want the result to be 02/08/2018 10:37, you want to take 3 hours from the first date?
– novic
@Virgilionovic yes.
– Matheus Miranda