No, the blur is a filter, so there is no way to undo, note that even applying filter: none will not work, see an example just to understand the problem (This is not the solution, it’s a test):
html, body {
    height: 100%;
}
.main {
    min-height: 100%;
    background: url(https://i.stack.imgur.com/Pk9BV.jpg);
    -webkit-filter: blur(5px);
        -ms-filter: blur(5px);
            filter: blur(5px);
}
.main .content {
     filter: none;
}
<div class="main">
     <div class="content">xxxx</div>
</div>
 
 
How to solve
It is possible simulate one background using position: relative;+position: absolute;
Would look like this:
Note that in the .main you can put anything, text, image, etc, and on .main-bg will be the elements you want to apply the filter, such as blur for example
html, body {
    height: 100%;
}
.main-bg {
    position: absolute;
    left: 0;
    top: 0;
    z-index: 100;
    width: 100%;
    height: 100%;
    background: url(https://i.stack.imgur.com/Pk9BV.jpg);
    -webkit-filter: blur(5px);
        -ms-filter: blur(5px);
            filter: blur(5px);
}
.main {
    position: relative;
    z-index: 101; /*posiciona acima do */
}
<div class="main">
     foo bar baz foo bar baz foo bar baz<br>
     foo bar baz foo bar baz foo bar baz<br>
     foo bar baz foo bar baz foo bar baz<br>
     foo bar baz foo bar baz foo bar baz<br>
     <img src="https://i.stack.imgur.com/Pk9BV.jpg">
</div>
<div class="main-bg"></div>
 
 
							
							
						 
Can not block, but can simulate. Put image with Blur in the background, and image without Blur in modal.
– Bacco